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  • OREOcube (ORganics Exposure in Orbit): in-situ UV-Vis spectroscopy of organic compounds on the International Space Station

    Paper number

    IAC-18,A1,6,8,x44328

    Author

    Mr. Sebastian Wolf, Germany, Free University of Berlin

    Coauthor

    Dr. Andreas Elsaesser, Germany, Free University of Berlin

    Coauthor

    Dr. Richard Quinn, United States, National Aeronautics and Space Administration (NASA), Ames Research Center

    Coauthor

    Dr. Antonio J Ricco, United States, National Aeronautics and Space Administration (NASA)

    Coauthor

    Dr. Farid Salama, United States, National Aeronautics and Space Administration (NASA), Ames Research Center

    Coauthor

    Prof. Alexander Kros, The Netherlands, University of Leiden

    Coauthor

    Prof. Herve Cottin, France, LISA

    Coauthor

    Dr. Zita Martins, Portugal, Instituto Superior Técnico

    Coauthor

    Dr. Louis D'Hendecourt, France, IAS

    Coauthor

    Dr. Emmanuel Dartois, France, IAS

    Coauthor

    Prof. Bernard Foing, The Netherlands, ESA/ESTEC, ILEWG & VU Amsterdam

    Coauthor

    Prof. Mark Sephton, United Kingdom, Imperial College London

    Coauthor

    Prof. Marco Spaans, The Netherlands, University of Groningen

    Year

    2018

    Abstract
    OREOcube is a next generation exposure platform with {\it in-situ} spectroscopic instrumentation, to be placed on the exterior of the International Space Station (ISS). OREOcube is part of a new European space exposure facility, which is currently under development by the European Space Agency. The anticipated launch is scheduled for 2020.
    
    The scientific focus of OREOcube is to study the carbon chemistry of astrobiologically interesting compounds directly in space. This avoids the limitations and technical challenges of laboratory simulation experiments on ground. Via {\it in-situ} UV-Vis spectroscopy, photochemical changes of organic/inorganic dual layer thin films will be monitored for a duration up to 18 months. Afterwards, samples will return to Earth for further in-depth chemical analysis. With each specific experiment on the OREOcube platform, we aim to understand the photostability of potential biomarkers and the formation of decomposition products. Furthermore, we will investigate the role minerals and inorganic surfaces play in these photochemical decomposition processes.
    
    Currently pre-flight experiments are being performed in order to select and test flight candidates. As a subset, we will show ground simulation results of organic molecules belonging to the class of porphyrins, quinones and amino acids, important molecules found in terrestrial organisms. Thin films of organic molecules will be in contact with iron oxide and mineral surfaces during irradiation, simulating a Mars-soil environment. The organic/inorganic composite films will be hermetically sealed within a so-called sample cell, which can be filled with gas at various pressures simulating Martian atmospheric conditions. Upon irradiation in the laboratory with simulated solar light, photochemical changes of the organics will be monitored and analysed via UV-Vis spectroscopy. By measuring {\it in-situ} the changes in the UV-Vis spectra of samples as a function of time, OREOcube will provide data sets that capture critical kinetic and mechanistic details of sample reactions that are not obtainable with the current exposure facilities on the ISS.
    Abstract document

    IAC-18,A1,6,8,x44328.brief.pdf

    Manuscript document

    IAC-18,A1,6,8,x44328.pdf (🔒 authorized access only).

    To get the manuscript, please contact IAF Secretariat.